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Mechanistic investigation of 9-bromoanthracene photodimers as initiators in atom transfer radical polymerization

✍ Scribed by Amanda C. Roof; Eric S. Tillman; Raleigh E. Malik; Alissa M. Roland; Daniel J. Miller; Louis R. Sarry

Book ID
108249403
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
265 KB
Volume
47
Category
Article
ISSN
0032-3861

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## Abstract Slow initiation from the bridgehead radical in atom transfer radical polymerization (ATRP) reactions initiated by 9‐bromoanthracene photodimers leads to polymers' products possessing high PDI values and higher than expected $\overline M \_{\rm n}$ values. We report here the effects of c