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Photodimers of 9-Haloanthracenes as Initiators in Atom Transfer Radical Polymerization: Effect of the Bridgehead Halogen

✍ Scribed by Eric S. Tillman; Daniel J. Miller; Amanda C. Roof

Book ID
106001224
Publisher
Springer
Year
2007
Tongue
English
Weight
469 KB
Volume
58
Category
Article
ISSN
0170-0839

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## Abstract Slow initiation from the bridgehead radical in atom transfer radical polymerization (ATRP) reactions initiated by 9‐bromoanthracene photodimers leads to polymers' products possessing high PDI values and higher than expected $\overline M \_{\rm n}$ values. We report here the effects of c