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Atom Transfer Radical Polymerization of Styrene Using Multifunctional Iniferter Reagents as Initiators

✍ Scribed by Zhang, Wei; Wang, Chengchao; Li, Daoguang; Song, Qing; Cheng, Zhenping; Zhu, Xiulin

Book ID
120440839
Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
263 KB
Volume
261
Category
Article
ISSN
1022-1360

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Atom transfer radical polymerizations of
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## Abstract Three novel iniferter reagents were synthesized and used as initiators for the polymerizations of methyl methacrylate (MMA) and styrene (St) in the presence of copper(I) bromide and __N,N,N__β€²,__N__β€³,__N__″‐pentamethyldiethylenetriamine at 90 and 115Β°C, respectively. All the polymerizat

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## Abstract **Summary:** Bifunctional initiators can produce polymers with higher molecular weight at higher initiator concentrations than monofunctional initiators. In this study, we developed a mathematical model for ATRP with bifunctional initiators. The most important reactions in ATRP were inc