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Mechanistic implications of the stereochemistry of singlet oxygen-olefin reactions

✍ Scribed by Lawrence B. Harding; William A. Goddard III

Publisher: Elsevier Science
Year: 1978
Tongue: French
Weight: 295 KB
Volume: 19
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)85384-3

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✦ Synopsis

We analyze the stereoselectivity of singlet oxygen-olefin reactions, concluding that a biradical peroxyl intermediate is involved and that experimental results are inconsistent with perepoxide intermediates.

Recently Conia et al. ' have reported the results of a series of experiments on the reaction of singlet oxygen with methoxy-substituted olefins.

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