Reaction of singlet oxygen with thiirane: Implication for a spirodioxathiirane intermediate
โ Scribed by Wataru Ando; Hideki Sonobe; Takeshi Akasaka
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 218 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
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Photooxygenation of tricyclo[3.3.l.l]decanone azine ( adamantanone azine ) afforded, in addition to adamantanone, 4-oxahomoadamantan-5-one derived from a dioxirane intermediate via a non-radical pathway. The reaction of singlet oxygen with conjugated dienes has been extensively studied, 1) but rela
Current interest in the reactions of singlet oxygen with heterocyclic systems prompts us to describe some of our own efforts in this area.' The marked reactivity of singlet oxygen with cis-dienes is well documented,' and this behavior suggested that it might be possible to obtain a reaction between