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Mechanisms of the reactions of singlet molecular oxygen with olefins

✍ Scribed by Kizashi Yamaguchi; Takayuki Fueno; Hideo Fukutome


Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
438 KB
Volume
22
Category
Article
ISSN
0009-2614

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✦ Synopsis


On the basis of the spin-and space-symmetry conservation criteria proposed previously, the cyclo~~~ition reactions of singlet molecular osy~en toward olehs and the thermal decomposition of dioxclane are characterized with respect to the mechanistic feature (conctrted, zwitterionic or biradical). The results are wholly colnpatible with observation


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