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Mechanisms of the cleavage of the C-N bond in substituted amines

โœ Scribed by Ya. Yu. Polis

Book ID
112330662
Publisher
Springer US
Year
1970
Tongue
English
Weight
75 KB
Volume
6
Category
Article
ISSN
0009-3122

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๐Ÿ“œ SIMILAR VOLUMES

Oxidative Cโ€“C bond cleavage of N-alkoxyc
Oxidative Cโ€“C bond cleavage of N-alkoxycarbonylated cyclic amines by sodium nitrite in trifluoroacetic acid
โœ Osamu Onomura; Atsushi Moriyama; Kazuhiro Fukae; Yutaka Yamamoto; Toshihide Maki ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 180 KB

Oxidative carbon-carbon bond cleavage of N-alkoxycarbonylated cyclic amines was accomplished by NaNO 2 in TFA to afford x-amino carboxylic acid in high yield. Optically active 3-hydroxypiperidine derivatives and 3-pipecolinate were converted to enantiomerically pure (R)-4-amino-3-hydroxybutanoic aci