Oxidative carbon-carbon bond cleavage of N-alkoxycarbonylated cyclic amines was accomplished by NaNO 2 in TFA to afford x-amino carboxylic acid in high yield. Optically active 3-hydroxypiperidine derivatives and 3-pipecolinate were converted to enantiomerically pure (R)-4-amino-3-hydroxybutanoic aci
Photochemical Release of Amines by C,N-Bond Cleavage.
β Scribed by Ralph O. Schoenleber; Bernd Giese
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 80 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Tryptophan derivatives & undergo with ease the oxidative C,-Cs bond cleavage by pyrimido[5,4-glpteridine N-oxide 2 under irradiation with UV-visible light in the presence of acid-catalyst to give 3-indolecarboxaldehydes 2 and the corresponding glycine derivatives 4.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v