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Reactivity of Arylic Carbanions Generated by Reductive Cleavage of C—N Bond of N,N-Dimethylanilines.

✍ Scribed by Ugo Azzena; Manuela Cattari; Giovanni Melloni; Luisa Pisano

Publisher
John Wiley and Sons
Year
2004
Weight
110 KB
Volume
35
Category
Article
ISSN
0931-7597

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Substituent effects on one-bond 15N13C c
Substituent effects on one-bond 15N13C couplings in N,N-dimethylanilines and nitrobenzenes. Effect of steric inhibition of conjugation
✍ T. Axenrod; C. M. Watnick; M. J. Wieder; S. Duangthai; G. A. Webb; H. J. C. Yeh; 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 466 KB

## Abstract The ^1^__J__(^15^N^13^C) values for a series of ring‐substituted __N__,__N__‐dimethylaniline‐^15^N derivatives and a series of nitrobenzene‐^15^N derivatives were measured from the ^13^C spectra. In the nitrobenzenes, small changes in ^1^__J__(^15^N^13^C) are attributed to the inductive