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Mechanisms of substitution reactions at sulfinyl sulfur. VI. Kinetics of the reaction of mercaptans with aryl sulfinyl sulfones

โœ Scribed by Kice, John L.; Campbell, J. Douglas

Book ID
127198639
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
505 KB
Volume
36
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES

Mechanisms of substitution reactions at
Mechanisms of substitution reactions at sulfinyl sulfur. Concomitant electrophilic and nucleophilic catalysis of the hydrolysis of p-toluenesulfinyl p-tolyl sulfone
โœ John L. Kice; Giancarlo Guaraldi ๐Ÿ“‚ Article ๐Ÿ“… 1966 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 258 KB

In investigating further the role of a sulfinyl sulfone (I) as an intermediate in the disproportion&ion of an aryl sulfinic acid (1,2) we have measured the rate of hydrolysis of Ia (eq. 1) in acetic acid-l% water as solvent. In the course of this work we have discovered that the rate