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Mechanisms of substitution reactions at sulfinyl sulfur. Concomitant electrophilic and nucleophilic catalysis of the hydrolysis of p-toluenesulfinyl p-tolyl sulfone

✍ Scribed by John L. Kice; Giancarlo Guaraldi

Book ID: 104214168
Publisher: Elsevier Science
Year: 1966
Tongue: French
Weight: 258 KB
Volume: 7
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)72911-x

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✦ Synopsis

In investigating further the role of a sulfinyl sulfone (I) as an intermediate in the disproportion&ion of an aryl sulfinic acid (1,2) we have measured the rate of hydrolysis of Ia (eq. 1) in acetic acid-l% water as solvent. In the course of this work we have discovered that the rate

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