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Correction. Mechanisms of Substitution Reactions at Sulfinyl Sulfur. Solvolysis of Aryl Sulfinyl Sulfones in Acetic Acid-Water

✍ Scribed by Kice, John; Guaraldi, Giancarlo

Book ID: 126985959
Publisher: American Chemical Society
Year: 1967
Tongue: English
Weight: 165 KB
Volume: 32
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo01286a612

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✍ Kice, John L.; Guaraldi, Giancarlo 📂 Article 📅 1966 🏛 American Chemical Society 🌐 English ⚖ 661 KB

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✍ John L. Kice; Giancarlo Guaraldi 📂 Article 📅 1966 🏛 Elsevier Science 🌐 French ⚖ 258 KB

In investigating further the role of a sulfinyl sulfone (I) as an intermediate in the disproportion&ion of an aryl sulfinic acid (1,2) we have measured the rate of hydrolysis of Ia (eq. 1) in acetic acid-l% water as solvent. In the course of this work we have discovered that the rate