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Mechanisms of SNi reactions. Effect of aralkyl group structure on ion-pair return in the decomposition of aralkyl thiocarbonates

โœ Scribed by Kice, John L.; Hanson, Gary C.

Book ID
127283253
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
830 KB
Volume
38
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES

Mechanisms of SNi reactions. the decompo
Mechanisms of SNi reactions. the decomposition of aralkyl thiocarbonates
โœ John L. Kice; Richard A. Bartsch ๐Ÿ“‚ Article ๐Ÿ“… 1963 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 224 KB

TFIE DECOMPOSITION of alkyl chlorocarbonates (equation 1) is one of the standard examples of an SNi reaction. The response of rate to structural R-O-$-Cl A b R-Cl + COs (1) . . , 1, g, 4899 (1960). (4) S.

Mechanisms of SNi reactions. Stereochemi
Mechanisms of SNi reactions. Stereochemical evidence for a two step mechanism for the decomposition of aralkyl thiocarbonates
โœ John L. Kice; Mary A. Dankleff ๐Ÿ“‚ Article ๐Ÿ“… 1966 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 145 KB

work (1) haa Indicated that there is a substantial elmllarlty between the mechanism of the thermal decomposition of aralkyl thiocarbonates (ep. 1) and the me&a&m of the decomposition of chlorocarbonates (cq. 2). The latter reaction is usually cited as a typical