𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Mechanisms of SNi reactions. Stereochemical evidence for a two step mechanism for the decomposition of aralkyl thiocarbonates

✍ Scribed by John L. Kice; Mary A. Dankleff

Book ID
104250249
Publisher
Elsevier Science
Year
1966
Tongue
French
Weight
145 KB
Volume
7
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

work (1) haa Indicated that there is a substantial elmllarlty between the mechanism of the thermal decomposition of aralkyl thiocarbonates (ep. 1) and the me&a&m of the decomposition of chlorocarbonates (cq. 2). The latter reaction is usually cited as a typical

πŸ“œ SIMILAR VOLUMES

Mechanisms of SNi reactions. the decompo
Mechanisms of SNi reactions. the decomposition of aralkyl thiocarbonates
✍ John L. Kice; Richard A. Bartsch πŸ“‚ Article πŸ“… 1963 πŸ› Elsevier Science 🌐 French βš– 224 KB

TFIE DECOMPOSITION of alkyl chlorocarbonates (equation 1) is one of the standard examples of an SNi reaction. The response of rate to structural R-O-$-Cl A b R-Cl + COs (1) . . , 1, g, 4899 (1960). (4) S.