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.pi. Groups in ion pair bonding. Effect of the cation on the structural and spectroscopic properties of fluorenyl ion pairs

✍ Scribed by Zerger, R.; Rhine, W.; Stucky, G. D.

Book ID
126818757
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
996 KB
Volume
96
Category
Article
ISSN
0002-7863

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The changes in the Raman spectra of aqueous solutions of I, in HI (1:l mole ratio) with changing concentration, have been shown to be a result of ion-pairing: H++I,=H+I;. The anomalous high frequency stretching band of the solute at 172 cm -' for these solutions arises mainly from stretching of the