𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Mechanisms of enzymatic CO bond cleavages in deoxyhexose biosynthesis

✍ Scribed by Xuemei He; Hung-wen Liu


Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
153 KB
Volume
6
Category
Article
ISSN
1367-5931

No coin nor oath required. For personal study only.

✦ Synopsis


In the past few years, significant progress has been made in our understanding of the biosynthesis of deoxyhexoses. Mechanistic studies have revealed how enzymes can cleave CbondO bonds of a hexose substrate to make unusual sugars. The increasing amount of knowledge about the biosynthesis of deoxysugars may allow the assembly of a repertoire of novel sugar structures through recruitment and collaborative action of genes from a variety of biosynthetic pathways to create diverse secondary metabolites in our search for novel antibiotic/antitumour agents.


📜 SIMILAR VOLUMES


Demonstration of reversible CC bond cle
✍ Brian A. Marples; John A. Rudderham; Alexandra M.Z. Slawin; Andrew J. Edwards; N 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 157 KB

The incorporation of a stereochemical probe into aryl substituted oxiranylcarbinyl radicals has demonstrated that the C-C bond cleavage in these systems is reversible, and that it can occur even when no products of C-C cleavage are obtained.

Importance of axial ligand in meso-tetra
✍ Ken Fujimori; Seiichi Fujiwara; Toshikazu Takata; Shigeru Oae 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 268 KB

Abd.Ura&: Am&M, edpeciaeey inkiazoik, wet~e dound to be e..~evu%L in the memo-teakaphenyl-po~p&nato~on(llIJ pkomoted demtihytion 06 N,N-din&hyLanXine N-oxide though the PoLonounki ape heU&Ofl and in the cumene hy&opehoxidc dependeti oxidtive demeXhyLuZion 06 N, N-c&methyLaWne in ckchX.o~omtihane. #h