Facile cleavage of a CC bond in a dinuclear nickel complex
✍ Scribed by Christophe J. Lawrie; Heidi E. Dankosh; Barry K. Carpenter
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 243 KB
- Volume
- 411
- Category
- Article
- ISSN
- 0022-328X
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📜 SIMILAR VOLUMES
The incorporation of a stereochemical probe into aryl substituted oxiranylcarbinyl radicals has demonstrated that the C-C bond cleavage in these systems is reversible, and that it can occur even when no products of C-C cleavage are obtained.
Novel cleavage patterns of C C bonds and C Si bonds were achieved via alkyne-or ketone-induced reactions of zirconacyclobutene-silacyclobutene fused ring compounds; thermodynamically favored six-membered zirconacyclohexadiene derivatives were formed in excellent yields from the four-membered zircona