Demonstration of reversible CC bond cleavage in oxiranylcarbinyl radicals

✍ Scribed by Brian A. Marples; John A. Rudderham; Alexandra M.Z. Slawin; Andrew J. Edwards; Nicholas W. Hird

• Publisher: Elsevier Science
• Year: 1997
• Tongue: French
• Weight: 157 KB
• Volume: 38
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(97)00673-4

✦ Synopsis

The incorporation of a stereochemical probe into aryl substituted oxiranylcarbinyl radicals has demonstrated that the C-C bond cleavage in these systems is reversible, and that it can occur even when no products of C-C cleavage are obtained.