Organoaluminum-promoted rearrangement of
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Keiji Maruoka; Junko Sato; Hiroshi Banno; Hisashi Yamamoto
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Article
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1990
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Elsevier Science
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French
β 206 KB
## The Claisen rearrangement of ally1 phenyl ethers with exceptionally bulky, oxygenophilic methylaluminum bis(4-bronro-2,6-di-terr-buty$henoxide) (reagent A) is found to exhibit an unusual behavior twt observable in the ordinary thermal and LAMS acid-induced rearrangement. The Claisen rearrangem