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Demonstration of the Participation of Free Radicals in the Rearrangement of Benzyl Phenyl Ether

✍ Scribed by HICKINBOTTOM, W. J.


Book ID
109528343
Publisher
Nature Publishing Group
Year
1939
Tongue
English
Weight
112 KB
Volume
143
Category
Article
ISSN
0028-0836

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## Abstract A value of the enthalpy of formation of the phenoxy radical in the gas phase, Ξ”__H__Β°~,298K~ (Ο•OΒ·, g) = 11.4 Β± 2.0 kcal/mol, has been obtained from the kinetic study of the unimolecular decompositions of phenyl ethyl ether, phenyl allyl ether, and benzyl methyl etherTrivial names for et