Mechanism of the Radiolysis of Cyclohexane
β Scribed by Dipl.-Chem. Horst Herler
- Publisher
- John Wiley and Sons
- Year
- 1971
- Tongue
- English
- Weight
- 226 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0044-8249
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π SIMILAR VOLUMES
Received 8 May 1972 c\ rapid (I < 500 psec) transfer of singlet energy is observed in the picosecond pu!se radiolysis of dilu te (10V3-lo-' 51) solutions of aromatic solutes in cyclohesanz.
Previous experimental observations and new pulse ndiolyds results concemmg the high-mobfity positive ion in cycloh-e are examined\_ Apparent dir;agzrcernent among these observations concerning the existence of a high-mobility positive ion can be explained If there are two positive ions of major impo
It is confirmed by pulse radiolysis that emitting sokent excited states are produced in the radiolysis of n-hexane, me~~yI~ycIo~e~~ne and cyclohexane, The emission is quenched by benzene and benzene emission appears. Applying Stern-Volmcr kinetics to emissions from solvent, benzene and tolucne in cy