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Pulse radiolysis of cyclohexane: The identity of the high-mobility positive ion

✍ Scribed by Alexander D. Trifunac; Myran C. Sauer Jr.; Charles D. Jonah

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
431 KB
Volume
113
Category
Article
ISSN
0009-2614

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✦ Synopsis

Previous experimental observations and new pulse ndiolyds results concemmg the high-mobfity positive ion in cycloh-e are examined_ Apparent dir;agzrcernent among these observations concerning the existence of a high-mobility positive ion can be explained If there are two positive ions of major importance m cyclohexane radiolyti. l3e possibility is examined that the cCsH:z ion has a "normal" mobility and that hydride tisfcr or proton tisfer, involving c-C~H:~ or cCeHf3 respectively, is responsible for the observed h&h mobility_

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