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Radical formation in the pulse radiolysis of liquid cyclohexane: Time-resolved EPR-scavenging study

✍ Scribed by D.W. Werst; A.D. Trifunac

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 704 KB
Volume: 137
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(87)80237-3

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✦ Synopsis

The relative yields of cyclohexyl radical in pulse-irradiated liquid cyclohexane and cyclohexane solutions containing negatwe (C02) and positive charge scavengers (cis-and trans-decalin)

are measured via time-resolved EPR. Charge scavenging has a negligible effect on radical production. A mechanism of alkyl radical formation is suggested based on fragmentation of vibrationally excited cyclohexane radical cations.

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