✦ LIBER ✦

The yield of solvent excited states in the radiolysis of cyclohexane solutions

✍ Scribed by J.H. Baxendale; J. Mayer

Publisher: Elsevier Science
Year: 1972
Tongue: English
Weight: 246 KB
Volume: 17
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(72)87123-9

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✦ Synopsis

It is confirmed by pulse radiolysis that emitting sokent excited states are produced in the radiolysis of n-hexane, me~~yI~ycIo~e~~ne and cyclohexane, The emission is quenched by benzene and benzene emission appears. Applying Stern-Volmcr kinetics to emissions from solvent, benzene and tolucne in cyclohexane a very high energy transfer rate constant, viz., k = 2.8 X 10' r his1 set ^ 1 is obtained. The yield of the excited state of cyc?ohextane is not greater than 0.3, and it is conciuded that the major part of the excited states of other aromatics produced in cyclohesane solutions comes from ion ncutraliDtion.

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