Mechanism of the peroxyoxalate chemiluminescence reaction
β Scribed by P.J.M. Kwakman; G.J. de Jong; U.A.Th. Brinkman
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 602 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0165-9936
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The observation of light emission from bdnubm m an orgamc solvent as a result of the peroxyoxalate chemdummescence reaction IS reported for the first time The results presented herem indicate that blhrubm chemdummescence can be detected m N,N' dlmethylformamlde but not m chloroform, dlmethylsulfoxld
Several analytes such as the inorganic anions bromide, iodide, sulphite and nitrite and organic compounds as substituted anilines and sulphur compounds cause quenching of peroxyoxalate chemiluminescence. A detection method for liquid chromatography based on the quenching phenomenon has been develope
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