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Mechanism of the ferric ion catalyzed decomposition of hydrogen peroxide. Effect of organic substrates

✍ Scribed by Walling, Cheves.; Goosen, Andre.

Book ID
125496606
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
582 KB
Volume
95
Category
Article
ISSN
0002-7863

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The stoichiometry of O2 evolution in the Fe3+ catalyzed decomposition of H202 in dilute HCIOa a t high [FeS+]/[H202] ratios is 2H202 -+ 2H20 + O2 with no deficiency indicating accumulation of an intermediate complex. This and the observed kinetics are shown to be consistent with a "redox chain" but