✦ LIBER ✦

Oxygen evolution as a critical test of mechanism in the ferric-ion catalyzed decomposition of hydrogen peroxide

✍ Scribed by Cheves Walling; Michael Cleary

Publisher: John Wiley and Sons
Year: 1977
Tongue: English
Weight: 300 KB
Volume: 9
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550090408

No coin nor oath required. For personal study only.

✦ Synopsis

The stoichiometry of O2 evolution in the Fe3+ catalyzed decomposition of H202 in dilute HCIOa a t high [FeS+]/[H202] ratios is 2H202 -+ 2H20 + O2 with no deficiency indicating accumulation of an intermediate complex. This and the observed kinetics are shown to be consistent with a "redox chain" but not a "complex" mechanism for the reaction.

📜 SIMILAR VOLUMES

The ferric ion catalyzed decomposition o

The ferric ion catalyzed decomposition of hydrogen peroxide in perchloric acid solution

✍ Cheves Walling; Tomas Weil 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 English ⚖ 395 KB 👁 1 views

## Abstract Predictions of the “redox” and “complex” schemes for the Fe^3+^ catalyzed decomposition of H~2~O~2~ have been compared with published and new experimental data by numerical integratior of the appropriate complete sets of differential equations. Apparent discrepancies for the redox schem