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The ferric ion catalyzed decomposition of hydrogen peroxide in perchloric acid solution

✍ Scribed by Cheves Walling; Tomas Weil

Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
395 KB
Volume
6
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

Predictions of the β€œredox” and β€œcomplex” schemes for the Fe^3+^ catalyzed decomposition of H~2~O~2~ have been compared with published and new experimental data by numerical integratior of the appropriate complete sets of differential equations. Apparent discrepancies for the redox scheme at high Fe^3+^/H~2~O~2~ ratios are shown to disappear in the complete treatment, and inconsistencies of the complex scheme with both kinetic data and spectroscopic measurements are pointed out.

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