The kinetics of the acid-catalysed hydrolysis of the [(imidazole)4Co(CO3) ] + ion was found to follow the rate law -dln[complex]/dt = k~K[H+]/(1 + K[H+]) in the 25-45 ~ range, [H +] 0.05-1.0 M range and I = 1.0 M. The reaction sequence consists of a rapid protonation equilibrium followed by the one-
Mechanism of the acid catalysed hydrolysis of the chromatopenta-amminecobalt(III) ion
β Scribed by Novelette P. Sadler; Tara P. Dasgupta
- Publisher
- Springer
- Year
- 1992
- Tongue
- English
- Weight
- 365 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0340-4285
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We recently reported' that acctanilide readily sulphonatcs in solutions of sulphuric acid > 70 per cent I& to form I+acetylsulphanilic acid , and noted that the rate of hydrolysis of this latter compound increased with increasing acidity beyond 80 per cent d= sulphuric acid. Ve have now prepared IG
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