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The reaction mechanism of the acid-catalysed autoxidation of xanthene to xanthylium ion

✍ Scribed by A. P. ter Borg; H. R. Gersmann; A. F. Bickel

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
770 KB
Volume
85
Category
Article
ISSN
0165-0513

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The kinetics of the acid-catalysed hydrolysis of the [(imidazole)4Co(CO3) ] + ion was found to follow the rate law -dln[complex]/dt = k~K[H+]/(1 + K[H+]) in the 25-45 ~ range, [H +] 0.05-1.0 M range and I = 1.0 M. The reaction sequence consists of a rapid protonation equilibrium followed by the one-