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Mechanism of Ruthenium (III) Catalysis of Periodate Oxidation of Aldoses in Aqueous Alkaline Medium

โœ Scribed by AshokKumar Singh; N. Chaurasia; Shahla Rahmani; Jaya Srivastava; Bharat Singh

Book ID
111576373
Publisher
Springer US
Year
2004
Tongue
English
Weight
218 KB
Volume
95
Category
Article
ISSN
1011-372X

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Osmium(VIII)/ruthenium(III) catalysis of
Osmium(VIII)/ruthenium(III) catalysis of periodate oxidation of acetaldehyde in aqueous alkaline medium
โœ Dasharath L. Kamble; Sharanappa T. Nandibewoor ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 103 KB ๐Ÿ‘ 2 views

Os(VIII) and Ru(III) catalysis of the periodate oxidation of acetaldehyde in aqueous alkaline medium was investigated. The catalytic efficiency is Ru(III) `Os(VIII). The product of oxidation in both cases is acetate and IO 3 ร€ . The stoichiometry is the same in both catalyzed reactions, i.e. [IO 4

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Kinetics of osmium(VIII) catalysis of periodate oxidation of DMF in aqueous alkaline medium
โœ Gangadhar H. Hugar; Sharanappa T. Nandibewoor ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Springer ๐ŸŒ English โš– 259 KB

The osmium(VIII) catalysed IO2 oxidation of DMF in aqueous alkaline medium follows the rate law: where K2 is the equilibrium constant of the reaction K 3 is the formation constant for the complex between DMF and [OsOs(OH)] 3-and k is the decomposition rate constant. The data suggest that the oxida