The kinetics of Ruthenium( Ill) chloride mediated oxidation of acetone, 2-butanone, 4-methyl-2-pentanone, 2-pentanone, cyclopentanone, and cyclohexanone by sodium periodate in aqueous HCIO, media was zero-order in I lo,-) and first-order in I ketone]. The reaction was independent of added I R u ( l
β¦ LIBER β¦
Kinetics and Mechanism of the Ruthenium (III) Catalysed Oxidation of Some Aliphatic and Cyclic Ketones by Periodate Ion in Aqueous Alkaline Medium: A Novel Behaviour of Ruthenium (III)
β Scribed by Subas C. Pati; Markandeswar Panda
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 359 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0037-9646
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with respect to the catalyst concentration is first. The reaction mechanism supposes the formation of a complex between the substrate and the catalyst active form . Subsequently, the complex thus formed slowly decomposes in the rate determining step to give carbonium ions and ruthenium hydride, sinc