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Mechanism of reactions of α-diazosulphones acid-catalysed hydrolysis of p-methoxyphenylsulphonyl diazomethane

✍ Scribed by B. Zwanenburg; J.B.F.N. Engberts; J. Strating

Publisher
Elsevier Science
Year
1964
Tongue
French
Weight
182 KB
Volume
5
Category
Article
ISSN
0040-4039

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✦ Synopsis

Recently a-diazosulphones' which are a new type of diazo compounds, were prepared by Strating and Van Leusenc. It is worthwhile to compare the reactivity of these compounds with that of other types of diazo compounds. Therefore, p-metholryphenylsulphonyl diazomethane (I) was subjected to acid-catalgsed hydrolysis, and the mechanism of this reaction investigated more closely. The reaction occurring is similar to that of diazoketones. P-cH3Oc6R4 2 SO CBN2 + H30* +p-CH30C6H4S02CH20R + N2 + H' I II Presumably, tpe reaction product II3 is partly dissociated into formaldehyde and p-methoxybenzenesulphinic acid.

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