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Mechanism of prooxidant reaction of vitamin E: kinetic, spectroscopic, and ab initio study of proton-transfer reaction

✍ Scribed by Nagaoka, Shinichi; Sawada, Kouhei; Fukumoto, Youji; Nagashima, Umpei; Katsumata, Shunji; Mukai, Kazuo

Book ID
120342903
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
760 KB
Volume
96
Category
Article
ISSN
0022-3654

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Mechanism of the OH–propene–O2 reaction:
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The reaction of OH radicals with olefins is known to be important in atmospheric chemistry. From experimental data a global mechanism has been proposed, but the regioselectivity of the products is uncertain. In this work, the OH-propene-O 2 reaction has been studied with ab initio molecular orbital