Ab Initio Studies of ClO x Reactions. 3. Kinetics and Mechanism for the OH + OClO Reaction
β Scribed by Xu, Zhen-Feng; Zhu, Rongshun; Lin, M. C.
- Book ID
- 127228794
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 296 KB
- Volume
- 107
- Category
- Article
- ISSN
- 1089-5639
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## Abstract The kinetics and mechanism of the following reactions have been studied in the temperature range 230β360 K and at total pressure of 1 Torr of helium, using the dischargeβflow mass spectrometric method: 1a: 1b: The following Arrhenius expression for the total rate constant was obtaine
The reaction of OH radicals with olefins is known to be important in atmospheric chemistry. From experimental data a global mechanism has been proposed, but the regioselectivity of the products is uncertain. In this work, the OH-propene-O 2 reaction has been studied with ab initio molecular orbital