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Mechanism of ligand substitution on five-coordinate iron and cobalt dithiolene complexes

โœ Scribed by D.A. Sweigart


Book ID
114041273
Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
418 KB
Volume
8
Category
Article
ISSN
0020-1693

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Ligand substitution at five-coordinate c
โœ D.A. Sweigart ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 226 KB

## The kinetics of l&and substitution on the jive-coordinate 1,2-dithiolene complexes [M(&C,(CF,)& X]' (M = Fe, Co; X = a phosphine or phosphite ) are reported. The mechanism is associative for z = 0 and dissociative for z = -1.