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Ligand substitution at five-coordinate centers. Reactions of neutral iron- and cobalt-dithiolene complexes

โœ Scribed by Sweigart, D. A.; Cooper, D. E.; Millican, J. M.

Book ID
120300005
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
495 KB
Volume
13
Category
Article
ISSN
0020-1669

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Ligand substitution at five-coordinate c
Ligand substitution at five-coordinate centers. Reactions of phosphine and phosphite adducts of the bis(trifluoromethyl)-1, 2-dithiolene iron and cobalt systems
โœ D.A. Sweigart ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 226 KB

## The kinetics of l&and substitution on the jive-coordinate 1,2-dithiolene complexes [M(&C,(CF,)& X]' (M = Fe, Co; X = a phosphine or phosphite ) are reported. The mechanism is associative for z = 0 and dissociative for z = -1.