Ligand substitution at five-coordinate centers. Reactions of phosphine and phosphite adducts of the bis(trifluoromethyl)-1, 2-dithiolene iron and cobalt systems

✍ Scribed by D.A. Sweigart

• Book ID: 104138255
• Publisher: Elsevier Science
• Year: 1976
• Tongue: English
• Weight: 226 KB
• Volume: 18
• Category: Article
• ISSN: 0020-1693
• DOI: 10.1016/s0020-1693(00)95600-7

✦ Synopsis

The kinetics of l&and substitution on the jive-coordinate 1,2-dithiolene complexes [M(&C,(CF,)& X]' (M = Fe, Co; X = a phosphine or phosphite

) are reported. The mechanism is associative for z = 0 and dissociative for z = -1.