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Mechanism of decarboxylation of 1,3-dimethylorotic acid revisited: Trapping of the reaction intermediate

✍ Scribed by Michael P. Nakanishi; Weiming Wu

Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 124 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)01331-8

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✦ Synopsis

The deearboxylafion of 1,3-dimethylorotic acid was investigated to study the nature of the reaction intermediate. 6-Benzyl-l,3-dimethyluracil was isolated when the deearboxylation was carried out in benzyl bromide, indicating.the involvement of a carbon-6 centered nucleophilic intermediate in the reaction pathway.

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