Kinetics and mechanism of the acid-catalysed decarboxylation ofcis-[Co(cyclen)CO3]+
β Scribed by Robert W. Hay; Bakir Jeragh
- Publisher
- Springer
- Year
- 1979
- Tongue
- English
- Weight
- 380 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0340-4285
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## Abstract This article proposes a mechanism of CO~2~ hydrate formation taking into account both diffusion and reaction, and gives an analysis of its kinetics. The most important assumptions on the model are that water dissolves into liquid CO~2~ and reacts to form CO~2~ hydrate, and that the hydr
The kinetics of the acid-catalysed hydrolysis of the [(imidazole)4Co(CO3) ] + ion was found to follow the rate law -dln[complex]/dt = k~K[H+]/(1 + K[H+]) in the 25-45 ~ range, [H +] 0.05-1.0 M range and I = 1.0 M. The reaction sequence consists of a rapid protonation equilibrium followed by the one-