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The reaction of benzofuroxan with p-anisylazide: Trapping of the o-dinitroso-intermediate

✍ Scribed by A.B. Bulacinski; E.F.V. Scriven; H. Suschitzky

Publisher: Elsevier Science
Year: 1975
Tongue: French
Weight: 107 KB
Volume: 16
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)91372-8

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✦ Synopsis

Previous studies using n.m.r. have indicated that benzofuroxan may tautomerise via g-dinitrosobenzene as shown, and the activation energy of this process has been measured'.

We recently reported the trapping of triplet arvlnitrenes bv some nitrosoarenes in boilino bromobenzeneL and thought that we could apply this method to demonstrate chemicallv the intermediacy of the c-dinitrosocompound.

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