## Abstract The mechanism of Ξ±βolefin hydroalumination by HAlBu^__i__^~2~, ClAlBu^__i__^~2~, and AlBu^__i__^~3~ in the presence of Cp~2~ZrCl~2~ catalyst has been studied. It was established that the key intermediate of the reaction is a bimetallic complex [Cp~2~ZrH~2~ Β· ClAlBu^__i__^~2~]~2~, which
Mechanism of Cp2ZrCl2-catalyzed olefin hydroalumination by alkylalanes
β Scribed by L. V. Parfenova; S. V. Pechatkina; L. M. Khalilov; U. M. Dzhemilev
- Publisher
- Springer
- Year
- 2005
- Tongue
- English
- Weight
- 774 KB
- Volume
- 54
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
The reduction of alkynols with LiAlH 4 in diglyme is a long known process leading to the formation of (E)-alkenols. We have, by serendipity, found that, in the presence of a catalytic amount (10%) of Cp 2 TiCl 2 , the stereoselectivity of the reaction is reversed, leading to the selective formation
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.