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Study on ethylene polymerization catalyzed by Cp2ZrCl2/carbon nanotube system

✍ Scribed by Xiaochen Dong; Li Wang; Tianxu Sun; Junfeng Zhou; Qiang Yang

Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
644 KB
Volume
255
Category
Article
ISSN
1381-1169

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## Abstract Summary: We report a simple method for tuning catalytic property of a metallocene‐based catalyst, Cp~2~ZrCl~2~, for ethylene polymerization by the direct adsorption of Cp~2~ZrCl~2~ onto multi‐walled carbon nanotubes (MWCNTs). The direct interactions between MWCNTs and the Cp rings of Cp

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## Abstract The slurry homopolymerization of ethylene catalyzed by a Cp~2~ZrCl~2~/MAO catalytic system was studied. A simple kinetic model including initiation, propagation, transfer to monomer and cocatalyst, spontaneous transfer and spontaneous deactivation was developed to predict dynamic yield