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Mechanism of asymmetric hydrogenation by rhodium complexes with unsymmetrical P-chirogenic bisphosphine ligands

✍ Scribed by Atsushi Ohashi


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
243 KB
Volume
14
Category
Article
ISSN
0899-0042

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πŸ“œ SIMILAR VOLUMES


The mechanism of asymmetric hydrogenatio
✍ Kazuo Achiwa; Yoko Ohga; Yoichi Iitaka; Hazime Saito πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 French βš– 225 KB

Effective catalytic asymmetric hydrogenations catalyzed by chiral pyrrolidinephosphine-rhodium complexes have been proven to be useful for the preparation of optically active a-amino acids @3-91%)2'3), isoquinoline salsolidine (45%)6) cc-hydroxy esters (78.5%)4'5), R-(-)-pantolactone C80.5-86.7%17'g