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The mechanism of asymmetric hydrogenation catalysed by rhodium (I) di pamp complexes.

✍ Scribed by John M. Brown; Penny A. Chaloner

Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
195 KB
Volume
19
Category
Article
ISSN
0040-4039

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✦ Synopsis

Asymmetric homogeneous hydrogenation of dehydroamino acid derivatives may b; effected in high optical yield by several rhodium complexes of chelating biphosphines

πŸ“œ SIMILAR VOLUMES

The mechanism of asymmetric hydrogenatio
The mechanism of asymmetric hydrogenations catalyzed by chiral pyrrolidinephosphine-rhodium complexes
✍ Kazuo Achiwa; Yoko Ohga; Yoichi Iitaka; Hazime Saito πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 French βš– 225 KB

Effective catalytic asymmetric hydrogenations catalyzed by chiral pyrrolidinephosphine-rhodium complexes have been proven to be useful for the preparation of optically active a-amino acids @3-91%)2'3), isoquinoline salsolidine (45%)6) cc-hydroxy esters (78.5%)4'5), R-(-)-pantolactone C80.5-86.7%17'g