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Mechanism of anodic oxide growth on bismuth

✍ Scribed by B. Lovreček; M. Metikoš-Hukovič

Book ID
108343362
Publisher
Elsevier Science
Year
1980
Weight
588 KB
Volume
106
Category
Article
ISSN
0022-0728

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Nucleation and growth of anodic oxide fi
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The rate of nucleation of the anodic oxide film on bismuth in 0.1 M NaOH is limited hy electrochemical reaction at the uncovered metal surface or surface diffusion to the periphery of a spreading oxide patch, not by incorporation into the growing lattice. Anodic oxide layers grown on bismuth consist

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✍ D.E. Williams; G.A. Wright 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 597 KB

The early stages in the formation of a continuous anodic layer of bismuth oxide on a solid bismuth electrode, in the pH range 5-14, were studied. The oxide covered the surface by the simultaneous thickening and spreading of patches. The metal surface was classified into two different areas with diff