The rate of nucleation of the anodic oxide film on bismuth in 0.1 M NaOH is limited hy electrochemical reaction at the uncovered metal surface or surface diffusion to the periphery of a spreading oxide patch, not by incorporation into the growing lattice. Anodic oxide layers grown on bismuth consist
Absorption edge and energy gap of anodic oxide films on bismuth
β Scribed by S. Ikonopisov; E. Klein; A. Stanchev; Ts. Nikolov
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 329 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0040-6090
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π SIMILAR VOLUMES
The early stages in the formation of a continuous anodic layer of bismuth oxide on a solid bismuth electrode, in the pH range 5-14, were studied. The oxide covered the surface by the simultaneous thickening and spreading of patches. The metal surface was classified into two different areas with diff
The transient poten+ response to a step chaage in current of both freshly prcpamd and aged bismuth ano& oxW films indxzted that the anodic 6lm had a non-stoichbamtric laya at the film-metal interfaa, the response rel%&ing the relaxation of sv charges of trapped electrons aad mobile ions. The idea is