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Mechanism for the formation of 2,3-butanediol stereoisomers in Bacillus polymyxa

โœ Scribed by Ui, Sadaharu; Masuda, Takahito; Masuda, Hiroshi; Muraki, Hiroyuki


Book ID
123241152
Publisher
Elsevier Science
Year
1986
Weight
577 KB
Volume
64
Category
Article
ISSN
0385-6380

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The reaction of 2,3-di-(3-pyridyl)-2,3-butanediol (1) in H 2 SO 4 was studied. It was found that the meso and racemic forms give mono-and bis-SO 3 addition products, which rearrange to a ketone (Metopirone ยฎ ) and two other major by-products. The formation of SO 3 addition products and a marked incr