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Discovery of a new mechanism of 2,3-butanediol stereoisomer formation in Bacillus cereus YUF-4

✍ Scribed by Sadaharu Ui; Takeshi Hosaka; Kazuhide Watanabe; Akio Mimura

Book ID
114294005
Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
552 KB
Volume
85
Category
Article
ISSN
0922-338X

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✍ Shogo Sakai πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 English βš– 405 KB

The mechanisms of the reactions of diborane with ammonia have been investigated by ab initio molecular orbital methods. The activation barrier of the formation of aminoborane, H,&NHr, from the adduct, H,B : NHs, of borane and ammonia is high (over 40 kcal/mol), because it is a reaction essentially