Mechanism and rate constants for the reactions of Cl atoms with HOCl, CH3OCl and tert-C4H9OCl
โ Scribed by A. Kukui; J. Roggenbuck; R. N. Schindler
- Book ID
- 112008606
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1997
- Tongue
- English
- Weight
- 475 KB
- Volume
- 101
- Category
- Article
- ISSN
- 0372-8323
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
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Rate constants have been measured at room temperature for the reactions of Cl atoms with formic acid and with the HOCO radical: Cl ฯฉ HCOOH !: HCl ฯฉ HOCO (R1) Cl ฯฉ HOCO !: HCl ฯฉ CO (R2) 2 Cl atoms were generated by flash photolysis of Cl 2 and the progress of reaction was followed by time-resolved i
A kinetic study of the reactions of H atoms with CH,SH and C2H6SH has been carried out at 298 K by the discharge flow technique with EPR and mass spectrometric analysis of the species. The pressure was 1 torr. It was found: k1 = (2.20 \* 0.20) x lo-'' for the reaction H + CH3SH (1) and k2 = (2.40 t